期刊
ENVIRONMENTAL TECHNOLOGY
卷 33, 期 9, 页码 1029-1036出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/09593330.2011.606280
关键词
NO; urea; La2O3; activated carbon fibre; room temperature
资金
- National Natural Science Foundation of China [50878080, 50908080]
- Scientific and Technological Special Project of Changsha City in China [K0902006-31]
- Scientific and Technological Project of Hunan Province in China [[2008]GK3118]
In this paper, catalytic samples of 10, 20, 30, 40 and 50%(w/w) urea/activated carbon fibre (AFC), 10% urea-5% La2O3/ACF, 10% urea-10% La2O3/ACF, 10% urea-15% La2O3/ACF, 20% urea-5% La2O3/ACF, 20% urea-10% La2O3/ACF, and 20% urea-15% La2O3/ACF were prepared and used for removal of NO under the condition of: NO, 500 ppm; O-2, 21%; N-2, balance, gas space velocity = 10000 m(3) . h(-1) . m(-3), total gas flow = 266.7 mL min(-1), temperature = 30 degrees C, relative humidity = 0%. The physical and chemical properties of the prepared catalysts were characterized by surface area measurements (BET) and scanning electron microscopy studies. Furthermore, the catalytic stability of 10% urea-5% La2O3/ACF under different concentrations of NO and O2 were also studied. The results showed that, among the prepared urea/ACF samples, 20% urea/ACF yielded the highest NO conversion at room temperature. Meanwhile, among the prepared urea-La2O3/ACF catalysts, 10% urea-5% La2O3/ACFyielded the highest NO conversion. Both 20% urea/ACF and 10% urea-5% La2O3/ACF could yield over 95% NO conversion at ambient temperature. However, 10% urea-5% La2O3/ACF had a more stable activity than that of 20% urea/ACF. The catalytic and characterization experimental results, including BET, thermogravimetric analysis and Fourier transform infrared analysis, showed that the NO selective catalytic reduction mechanism of urea-La2O3/ACF was different from that of ACF and urea/ACF. The NO was purified by ACF mainly by adsorption, whereas there was mainly a reduction reaction when NO was purified by urea/ACF or urea-La2O3/ACF. ACF-C was not only the catalyst but also the reducing agent for urea/ACF, whereas, for urea-La2O3/ACF, the catalytic centre was La2O3, and ACF was mainly the carrier. These differences resulted in the higher and more stable NO removal by 10% urea-5% La2O3/ACF.
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