期刊
ENVIRONMENTAL SCIENCE & TECHNOLOGY
卷 44, 期 14, 页码 5672-5676出版社
AMER CHEMICAL SOC
DOI: 10.1021/es1010779
关键词
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资金
- Ministry of Education, Science and Technology [R31-10013]
- Ministry of Education, Science & Technology (MoST), Republic of Korea [R31-2008-000-10013-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Novel biocidal polymer-functionalized TiO2 nanoparticles were prepared by surface-initiated photopolymerization using titania as an initiator. Vinyl monomer mixtures of nontoxic secondary amine-containing biocide] 2-(tert-butylamino)ethyl methacrylate and antifouling ethylene glycol dimethacrylate were used for the antimicrobial polymer shell. It was shown that the synthesized TiO2/poly[2-(tert-butylamino)ethyl methacrylateco-ethylene glycol dimethacrylate] core/shell nanoparticles had enhanced photocatalytic antibacterial properties compared to the pristine TiO2 nanoparticles due to the combined antibacterial activities of light-driven anti-infective TiO2 core and biocidal polymer shell. In the dark condition, the TiO2/biocidal polymer nanoparticles exhibited high antimicrobial efficiency (95.7%) against gram-positive S. aureus. Furthermore, during UV irradiation, the TiO2/biocidal polymer showed improved inhibition of bacterial growth against gram-negative E. coli and gram-positive S. aureus in comparison to the pristine TiO2 nanoparticles.
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