期刊
ENVIRONMENTAL SCIENCE & TECHNOLOGY
卷 43, 期 21, 页码 8119-8125出版社
AMER CHEMICAL SOC
DOI: 10.1021/es901859s
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Photooxidation of crude oil components is an important process that removes pollutants from the environment Polycyclic aromatic compounds (PACs) are known to be toxic to many life forms, but little is known about their photooxidation products in the aqueous phase. W e here identify a large number of photoproducts from 11 benzothiophenes, a polycyclic aromatic sulfur heterocycle that is a major representative of PACs in crude oil. The investigated compounds contain two to four methyl groups and an ethyl on an n-octyl group. In water, the products arise through oxidation of alkyl side chains to aldehydes and carboxylic acids on through an opening in one of the aromatic rings. The product analysis was performed using gas chromatography with mass spectrometric or atomic emission detection. The main product is always a sulfobenzoic acid, which strongly lowers the pH of the solution. With long alkyl substituents, surfactants are formed, which may possess solubilizing properties in water, The larger the number of alkyl groups, the faster is the photooxidation. Several of the identified acidic compounds were also found when whole crude oil was photooxidized, showing that simulation with individual compounds reflects the situation in whole crude.
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