期刊
ENVIRONMENTAL POLLUTION
卷 179, 期 -, 页码 194-200出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.envpol.2013.04.001
关键词
Brominated flame retardants; Organophosphorus flame retardants; BDE-209; Water; Risk assessment
资金
- Ministry of Education and Innovation of Spain [EEBB-2011-43641]
- Spanish Ministry [CTM2008-03263/TECNO]
- Natural Environment Research Council [ceh010010] Funding Source: researchfish
This study presents the occurrence and risk of PBDEs, new brominated and organophosphorus flame retardants along a river affected by urban and industrial pressures (River Aire, UK). Tris(2-choroethyl) phosphate (TCEP), tris(2-chloro-1-methylethyl) phosphate (TCPP), tris[2-chloro-1-(chloromethypethyl] phosphate (TDCP) and triphenyl phosphate (TPhP) were detected in all samples, with TCPP present at the highest concentrations, ranging from 113 to 26 050 ng L-1. BDE-209 was detected in most of the sampled sites, ranging from 17 to 295 ng L-1, while hexabromobenzene (HBB) and pentabromoethyl benzene (PBEB) were seldom detected. A risk quotients based on predicted no effect concentrations (PNEC) and flame retardants water concentration proved significant risk for adverse effects for algae, Daphnia and fish in sites close to industrial and urban sewage discharges. This study provides a protocol for the risk estimation of priority and new generation flame retardants based on river concentrations and toxicological values. (C) 2013 Elsevier Ltd. All rights reserved.
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