Analyses of the role of grain boundaries in mesoscale dynamic fracture resistance of SiC-Si3N4 intergranular nanocomposites

Silicon carbide (SiC)-silicon nitride (Si3N4) nanocomposites with SiC dispersions as well as Si3N4 matrix of mesoscale dimensions (similar to 1 mu m) are considered to have exceptional strength attributed to interactions of SiC dispersions With Si3N4 grain boundaries (GBs). However, an account of GBs on the strength of these nanocomposites is not available. In order to analyze this issue, cohesive finite element method (CFEM) based mesoscale dynamic fracture analyses Of SiC-Si3N4 nanocomposites with an explicit account of length scales associated with Si3N4 GBs, SiC particles, and Si3N4 grains are performed. Analyses indicate that primary mechanism of fracture in the nanocomposite microstructures is intergranular Si3N4 matrix cracking. GBs are responsible for crack deflection and accordingly damage is limited to a smaller geometric region in microstructures with GBs. On an average, a microstructure with GBs present is stronger than the corresponding microstructure with GBs removed. However, in cases where the second phase SiC particles are in the wake of microcracks the microstructure Without GB becomes stronger against fracture in comparison to the corresponding one with GBs owing to the crack bridging effect caused by the second phase SiC particles. (C) 2008 Elsevier Ltd. All rights reserved.