期刊
JOURNAL OF POWER SOURCES
卷 278, 期 -, 页码 693-702出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2014.12.075
关键词
Lithium titanate; Graphene; Anode; Rate performance; Lithium ion battery
资金
- NSFC [21231005]
- MOE [IRT-13R30]
- 111 Project [B12015]
- Research Fund for the Doctroral Program of Higher Education of China [20120031110001]
- Tianjin SciTech Project [10SYSYJC27600]
- [2011CB935900]
Small amount of reduce graphene oxide (rGO) nanosheets modified Li4Ti5O12 nanoparticles composite has been synthesized by a facile and environmental in-situ hydrothermal reaction with subsequent annealing. The small amount of rGO (only 1.2 wt. %) greatly improves the whole morphology and electrochemical performance of composite. The nanoparticles uniformly grow on the rGO nanosheets effective suppressing the agglomeration and enhancing the specific surface area. Meanwhile, the special discharge capacity is 187 mAh g(-1) at 1 C and the high rates discharge capacity is 128 mAh g(-1) at 80 C (discharge-charge time only 33s). In particular, the cells remain in good work condition after 2000 cycles at 80 C, which credibly evidence the excellent electrochemical performance as an anode for high-power LIBs. (C) 2014 Elsevier B.V. All rights reserved.
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