期刊
JOURNAL OF POWER SOURCES
卷 283, 期 -, 页码 389-396出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2015.02.151
关键词
Nitrogen-doped; Hierarchically porous carbon spheres; Metal-free; Oxygen reduction
资金
- NSFC [21373116, 21421001]
- Tianjin Natural Science Research Fund [13JCYBJC18300]
- RFDP [20120031110005]
- MOE Innovation Team of China [IRT13022]
Using hierarchically mesoporous silica spheres as a hard template and methyl violet as carbon and nitrogen source, nitrogen-doped hierarchically porous carbon spheres (N-HCS) are successfully prepared via a nanocasting method. The nitrogen-doped carbon spheres obtained after carbonization at 1000 C (N-HCS-1000) exhibit a hierarchically micro-meso-macroporous structure with a relatively high surface area (BET) of 1413 m(2) g(-1) and a notably large pore volume of 2.96 cm(3) g(-1). In an oxygen reduction reaction (ORR) in alkaline media, the N-HCS-1000 material exhibits excellent activity with high current density, and its onset potential is notably close to that of the commercial Pt/C catalyst. The efficient catalytic activity of this catalyst could be attributed to the high electrical conductivity of the nitrogen-doped carbon matrix as well as the hierarchically porous framework. This catalyst also exhibits better methanol crossover resistance and higher stability than the commercial Pt/C catalyst. (C) 2015 Elsevier B.V. All rights reserved.
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