期刊
JOURNAL OF POWER SOURCES
卷 276, 期 -, 页码 73-79出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2014.11.094
关键词
Li-ion battery anodes; High charge-discharge rates; Electrochemical impedance spectroscopy; Silicon-coated vertically aligned carbon nanofibers
资金
- NSF [CMMI-1100830]
- NASA [NNX13AD42A]
- NSF EPSCoR Award [EPS-0903806]
- State of Kansas
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1105986] Funding Source: National Science Foundation
- Directorate For Engineering
- Div Of Civil, Mechanical, & Manufact Inn [1100830] Funding Source: National Science Foundation
- Office of Integrative Activities
- Office Of The Director [0903806] Funding Source: National Science Foundation
This study reports of a multi-scale hierarchical lithium-ion battery (LIB) anode that shows a surprising increase in storage capacity at higher current rates from similar to 3C to similar to 8C. The anode, composed of forest-like vertically aligned carbon nanofibers coaxially coated with Si shells, is shown to obtain a storage capacity of 3000-3500 mAh (gsi)(-1) and greater than 99% coulombic efficiency at a 1C (or C/1) rate, leading to remarkable stability over 500 charge-discharge cycles. In contrast to other studies, this hierarchical LIB anode shows superior high-rate capability where the capacity decreased by less than 7% from similar to C/8 to similar to 3C rates and, more importantly, increased by a few percent from similar to 3C to similar to 8C rates, displaying a new phenomenon that becomes more evident after going through long cycles. Electron microscopy, Raman, and electrochemical impedance spectroscopy reveal that the electrode structure remains stable during long cycling and that this enhanced property is likely associated with the combination of the unique nanocolumnar microstructure of the Si coating and the vertical core-shell architecture. It reveals an exciting potential to develop high-performance lithium-ion batteries. (C) 2014 Elsevier B.V. All rights reserved.
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