Pyrolysis of municipal sewage sludges in a slowly heating and gas sweeping fixed-bed reactor

The pyrolysis of three municipal sewage sludges was carried out using a slowly heating and gas sweeping fixed-bed reactor in the temperature range between 300 degrees C and 700 degrees C. The study was aimed to characterize the gaseous and liquid products derived from three different sewage sludges and mainly to discuss the varieties of sewage sludges on the yields and compositions of the gaseous and liquid products. The pyrolysis in this reactor was observed to produce high yields of liquid (above 40 wt.% at 700 degrees C) that contained high proportions of oxygen-containing compounds and nitrogenated compounds, with minor monoaromatics and aliphatic compounds. The gas and liquid yields correlated with the volatile matter contents in the sludges. For all three sewage sludges, the oxygenated compounds were the principal liquid compounds which could be produced at a low temperature of 300 degrees C, while more of nitrogenated compounds and other compounds were formed at 700 degrees C depending on the varieties of sewage sludges. (C) 2014 Elsevier Ltd. All rights reserved.