期刊
JOURNAL OF POWER SOURCES
卷 285, 期 -, 页码 146-155出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2015.03.091
关键词
Natural abundance O-17 NMR; Chemical shift calculation; Ethylene carbonate; Propylene carbonate; Ethyl methyl carbonate; Solvation structure
资金
- Joint Center for Energy Storage Research (JCESR), an Energy Innovation Hub - U.S. Department of Energy, Office of Science, Basic Energy Sciences (BES)
- U.S. Department of Energy's (DOE's) Office of Electricity Delivery and Energy Reliability (OE) [57558]
- DOE's Office of Biological and Environmental Research (BER)
- National Natural Science Fund of China [21327001]
- Department of Energy [DE-AC05-76RLO1830]
Natural abundance O-17 NMR measurements were conducted on electrolyte solutions conisting of Li [CF3SO2NSO2CF3] (LiTFSI) dissolved in the solvents of ethylene carbonate (EC), propylene carbonate (PC), ethyl methyl carbonate (EMC), and their mixtures at various concentrations. It was observed that O-17 chemical shifts of solvent molecules change with the concentration of LiTFSI. The chemical shift displacements of carbonyl oxygen are evidently greater than those of ethereal oxygen, strongly indicating that Li+ ion is coordinated with carbonyl oxygen rather than ethereal oxygen. To understand the detailed molecular interaction, computational modeling of O-17 chemical shifts was carried out on proposed solvation structures. By comparing the predicted chemical shifts with the experimental values, it is found that a Li+ ion is coordinated with four double bond oxygen atoms from EC, PC, EMC and TFSI- anion. In the case of excessive amount of solvents of EC, PC and EMC the Li+ coordinated solvent molecules are undergoing quick exchange with bulk solvent molecules, resulting in average O-17 chemical shifts. Several kinds of solvation structures are identified, where the proportion of each structure in the liquid electrolytes investigated depends on the concentration of LiTFSI. (C) 2015 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据