期刊
ENERGY & FUELS
卷 27, 期 7, 页码 3802-3810出版社
AMER CHEMICAL SOC
DOI: 10.1021/ef400527k
关键词
-
资金
- DONG energy A/S, Energinet.dk
- DTU
Fast pyrolysis of lignin from an ethanol plant was investigated on a lab scale pyrolysis centrifuge reactor (PCR) with respect to pyrolysis temperature, reactor gas residence time, and feed rate. A maximal organic oil yield of 34 wt % dry basis (db) (bio-oil yield of 43 wt % db) is obtained at temperatures of 500-550 degrees C, reactor gas residence time of 0.8 s, and feed rate of 5.6 g/min. Gas chromatography mass spectrometry and size-exclusion chromatography were used to characterize the chemical properties of the lignin oils. Acetic acid, levoglucosan, guaiacol, syringols, and p-vinylguaiacol are found to be major chemical components in the lignin oil. The maximal yields of 0.62, 0.67, and 0.38 wt % db were obtained for syringol, p-vinylguaiacol, and guaiacol, respectively. The reactor temperature effect was investigated in a range of 450-600 degrees C and has a considerable effect on the observed chemical components and molecular mass distribution of the lignin oils. The obtained lignin oil has a very different components composition when compared to a beech wood oil.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据