期刊
JOURNAL OF POWER SOURCES
卷 289, 期 -, 页码 168-183出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2015.04.128
关键词
Lithium-ion battery; Thin film electrode; De lamination initiation; Critical size
资金
- National Science Foundation of China [11332005, 11172159]
- Shanghai Municipal Education Commission, China [13ZZ070]
- China Scholarship Council
The state of charge (SOC) or the depth of discharge (DOD) to and the time to delamination onset and the critical size for delamination, which are potentially important in lithium ion battery design for preventing the patterned thin film electrodes from delamination, are investigated. A theoretical approach based on the cohesive model is proposed to formulate the time to and the SOC (or DOD) to delamination onset, as well as the critical size for patterned disk-like electrodes. It is found that for negative electrode the delamination initiation is dominated by mode-II during cell charging and by mode-I during cell discharging. For positive electrode both delamination modes are theoretically possible during cell charging. When the electrochemical load factor is very high, the mode-I delamination is possible and an optimal size of electrodes exists for a given maximum (i) over bar. The SOC to mode-II delamination onset decreases significantly with increasing dimensionless radius, being independent of (i) over bar. When the mode-II is the dominated mode the critical size for delamination exists, and a formula for the critical size for delamination has been deduced, which is proportional to interface ductility and inversely proportional to maximum volumetric strain. (C) 2015 Elsevier B.V. All rights reserved.
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