期刊
ENERGY & ENVIRONMENTAL SCIENCE
卷 11, 期 11, 页码 3157-3162出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ee01651h
关键词
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资金
- National Natural Science Foundation of China [51374255, 51572299, 51802356]
- Innovation-Driven Project of Central South University [2018CX004]
Aqueous zinc-ion batteries (ZIBs) show conspicuous potential in large-scale energy storage systems due to their cost-effectiveness and environmentally friendliness. Yet developmental cathodes in aqueous ZIBs suffer from sluggish Zn2+ diffusion kinetics. Herein, we introduce an effective strategy by the chemical intercalation of Li+ into the interlayer of V(2)O(5)nH(2)O, i.e. Li(x)V(2)O(5)nH(2)O (LVO), with enlarged layer spacing and fast Zn2+ diffusion. As a cathode in aqueous ZIBs with a 2 M ZnSO4 electrolyte, the cotton-like LVO-250 demonstrates high rate capacities and excellent cycling performance (232 mA h g(-1) after 500 cycles at 5 A g(-1), and 192 mA h g(-1) after 1000 cycles at 10 A g(-1)). The electrochemical reaction kinetics and zinc storage mechanism are investigated in detail.
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