期刊
ENERGY & ENVIRONMENTAL SCIENCE
卷 7, 期 2, 页码 768-778出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ee42704h
关键词
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资金
- Natural Science and Engineering Research Council of Canada (NSERC)
- General Motors of Canada
- Canada Research Chair (CRC) Program
- Canadian Foundation for Innovation (CFI)
- Ontario Research Fund (ORF)
- Early Researcher Award (ERA)
- University of Western Ontario
LiNi1/3Co1/3Mn1/3O2 (NMC) is a highly promising cathode material for use in lithium ion batteries; unfortunately, its poor cycling performance at high cutoff voltages hinders its commercialization. In this study, for the first time, we employ atomic layer deposition (ALD) to coat lithium tantalum oxide, a solid-state electrolyte, with varying thicknesses on NMC in an attempt to improve battery performance. Our results indicate that utilization of a solid-state electrolyte as a coating material for NMC significantly improves performance at high cutoff voltages but is strongly dependent on coating thicknesses. Our investigation revealed that a thicker coating proved to be beneficial in preventing cathode material dissolution into the electrolyte and aided in maintaining the microstructure of NMC. Consequently, a thicker ALD coating resulted in increased electrochemical impedance of the cathode. The results of this study indicate that an optimized coating thickness is needed in order to strike a balance between maintaining structural stability while minimizing electrochemical impedance. The coating thicknesses are functionally specific, and for the best improvement of a cathode, a particular coating thickness should be sought.
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