期刊
ENERGY & ENVIRONMENTAL SCIENCE
卷 6, 期 1, 页码 92-96出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ee23057g
关键词
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资金
- Max Planck Society
- ERC Advanced Grant
- Alexander von Humboldt Foundation
- Federal Ministry of Education and Research
- Excellence Initiative by the German federal and state governments to promote science and research at German universities
Cellulose is both insoluble in water and resistant against hydrolysis. These features pose major problems for its conversion into platform chemicals. Herein, we demonstrate that mechanocatalytic, solid-state depolymerization combined with hydrogenolysis, in the presence of Ru/C in water, provides a highly efficient pathway for the production of sugar alcohols. This novel approach leads to yields of hexitols up to 94% at 150 degrees C in an overall process time of 4 h.
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