4.1 Article

Preparation and characterization of a tungsten(V) corrole dichloride complex

期刊

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
卷 19, 期 1-3, 页码 150-153

出版社

WORLD SCI PUBL CO INC
DOI: 10.1142/S1088424614500990

关键词

corrole; tungsten; early transition metal; air sensitive

资金

  1. UC-MEXUS Fellowship
  2. International Fulbright Science and Technology Fellowship

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The first example of a tungsten(V) corrole complex, (Mes(2)(p-OMePh)corrole)WCl2, has been prepared through a metathesis reaction of a lithium corrole (Mes(2)(p-OMePh)corrole)Li-3 center dot 6THF and WCl6. The product constitutes the first example of a tungsten(V) corrole complex synthesized under mild conditions and only the second example of a tungsten corrole complex.

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