期刊
ENERGY & ENVIRONMENTAL SCIENCE
卷 5, 期 10, 页码 9028-9033出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ee22358a
关键词
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资金
- National Research Foundation of Korea (NRF) [K20704000003TA050000310]
- Korean Ministry of Education, Science and Technology (MEST)
- International Cooperation program of the Korea Institute of Energy Technology Evaluation and Planning (KETEP)
- Korea Government Ministry of Knowledge Economy [2011T100100369]
- WCU (World Class University) program through the National Research Foundation of Korea
- Ministry of Education, Science and Technology [R31-10092]
- Korea Evaluation Institute of Industrial Technology (KEIT) [20118510010020] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Foundation of Korea [2007-00164] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Germanium holds great potential as an anode material for lithium ion batteries due to its large theoretical energy density and excellent intrinsic properties related to its kinetics associated with lithium and electrons. However, the problem related to the tremendous volume change of Ge during cycling is the dominant obstacle for its practical use. The previous research has focused on the improvement in mechanics associated with lithium without consideration of the kinetics. In this study, we demonstrate that the configuration engineering of the Ge electrode enables the improvement in kinetics as well as favorable mechanics. Two types of Ge inverse opal structures with porous walls and dense walls were prepared using a confined convective assembly method and by adjusting Ge deposition parameters in a chemical vapor deposition system. The Ge inverse opal electrode with porous walls shows much improved electrochemical performances, especially cycle performance and rate capability, than the electrode with dense walls. These improvements are attributed to a large free surface, which offers a facile strain relaxation pathway and a large lithium flux from the electrolyte to the active material.
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