期刊
ENERGY & ENVIRONMENTAL SCIENCE
卷 5, 期 11, 页码 9492-9495出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ee22178k
关键词
-
资金
- Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences
- Division of Photovoltaics, Office of Utility Technologies, U.S. Department of Energy [DE-AC36-08GO28308]
We report on the influence of water on the charge-carrier dynamics, photocurrent density-photovoltage (J-V) properties, and stability of dye-sensitized TiO2 solar cells (DSSCs) containing two different commonly used solvents. Adding water to the solvents was found to strongly alter the energy level alignments, retard recombination at the electrode-redox electrolyte interfaces, and increase the dark exchange current density. The added water had no effect on electron transport, however. The addition of water to the cells increased the photocurrent densities, photovoltages, and solar cell efficiencies but lowered the fill factors. Changes in the J-V characteristics were shown to result from the effects of water on the energetics and kinetics of transport and recombination in the DSSCs. Regardless of the solvent used in the DSSCs, the added water had no observed effect on the cell stability during 1000 h of continuous illumination under full sunlight (AM1.5).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据