期刊
ENERGY & ENVIRONMENTAL SCIENCE
卷 4, 期 10, 页码 4016-4022出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ee01680f
关键词
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资金
- National Natural Science Foundation of China [20925312]
- State Key Basic Research Program of PRC [2007CB209703, 2011CB935903]
- Shanghai Science & Technology Committee [09XD1400300, 10JC1401500, 08DZ2270500]
In this study, we report a facile process for preparing a carbon-coated nanosized Li4Ti5O12 nanoporous micro-sphere (CN-LTO-NMS) by a carbon pre-coating process combined with the spray drying method. The obtained material consists of a micron-size secondary sphere (10-20 mu m) accumulated by carbon-coated nanosized primary particles (similar to 200 nm). The nanosized primary particles and nano-thickness carbon layer uniformly coated over the particles as well as the interconnected nanopores greatly improve its rate capability. As a consequence, the resulting sample delivers a reversible capacity of 160 mAhg(-1) at 0.2 C, and shows remarkable rate capability by maintaining 79% of the capacity at 20 C (vs. 0.2 C), as well as excellent cycling stability with a capacity retention of 95% after 1000 cycles at 1 C rate (vs. 0.2 C).
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