期刊
ENERGY & ENVIRONMENTAL SCIENCE
卷 4, 期 5, 页码 1676-1679出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ee01117k
关键词
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资金
- National Basic Research Program of China (973 program) [2010CB227202]
- DICP [K2010B2]
- Liaoning Provincial Natural Science Foundation of China [20102227]
- Chinese Academy of Sciences [KGCX2-YW-398-1]
NF membranes, as an alternative to traditional ion exchange membranes, were first proposed and successfully prepared for VRBs based on a totally new concept of tuning the vanadium/proton selectivity via pore size exclusion. The results showed that membranes show increasing vanadium ion/proton (V/H) selectivity with decreasing pore size distribution. VRBs assembled with prepared NF membranes exhibited comparable performance to that of commercialized Nafion. The concept could potentially overcome the traditional restriction from ion exchange membranes and provide much more material options for VRB membranes.
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