期刊
ENERGY & ENVIRONMENTAL SCIENCE
卷 4, 期 9, 页码 3355-3358出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ee01886h
关键词
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资金
- French National Research Agency ANR
- French Ministry for Higher Education and Research
Hydrazine borane N2H4BH3 (HB, 15.4 wt% H) is a promising chemical hydrogen storage material. Herein, we report high-extent dehydrogenation of HB (i.e. hydrolysis of the group BH3 and decomposition of the moiety N2H4) in the presence of nickel-platinum nanoparticles (NPs) at 50 degrees C. Using Ni0.89Pt0.11 NPs, 5.79 +/- 0.05 equiv. H-2 + N-2 per HB can be released, corresponding to H-2 selectivity as high as 93 +/- 1%.
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