期刊
ENERGY & ENVIRONMENTAL SCIENCE
卷 4, 期 10, 页码 4155-4162出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ee01895g
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- ZT::Plus, Azusa, CA
The effect of the resonant impurity Tl, known to produce a high thermoelectric figure of merit in PbTe through a distortion of the density of states (DOS), is explored here in p-type PbTe1-xSx and PbTe1-ySey alloys with direct substitution of Tl for Pb, with the goal of combining its effect with a reduction of the thermal conductivity by alloy scattering. In PbTe1-xSx, the high DOS of PbTe:Tl (x = 0) is maintained up to x = 0.08, whereas the samples' mobility surprisingly increases monotonically with x. An optimal composition is found to reach zT = 1.6 at x = 0.08, using double-doping with both Tl and Na. The DOS of all PbTe1-ySey alloys decreases with y > 0. KKR-CPA electronic structure calculations were performed to enlighten the experimental trends in transport properties: thallium triggers the formation of free-electron-like excess DOS near Fermi level by coupling a Tl 6s-level to the Te p-levels. We ascribe the loss of resonant behavior to a change in overlap between these two levels due to the decrease of the lattice constant with x and y.
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