4.8 Article

High surface area, micro/mesoporous carbon particles with selectable 3-D biogenic morphologies for tailored catalysis, filtration, or adsorption

期刊

ENERGY & ENVIRONMENTAL SCIENCE
卷 4, 期 10, 页码 3980-3984

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ee02102h

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  1. U.S. Department of Energy, Office of Basic Energy Sciences [DE-SC0002245, DE-SC0001061]
  2. U.S. Air Force Office of Scientific Research [FA9550-05-1-0092, FA9550-09-1-0162]
  3. NSF

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Biogenic 3-D SiO2 micro-assemblies (diatom microshells) of low specific surface area (SSA, <2 m(2)g(-1)) have been transformed into 3-D replicas of high SSA C (>1300 m(2)g(-1)) and Pt-loaded C (>600 m(2)g(-1)) by a shape-preserving serial reaction process. Such high SSA micro-assemblies may be generated in a wide variety of selectable 3-D shapes for tailored catalysis, filtration, or adsorption for energy storage/production, water purification, and biofuel separation.

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