期刊
ENERGY & ENVIRONMENTAL SCIENCE
卷 4, 期 5, 页码 1708-1711出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ee00005e
关键词
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资金
- Engineering and Physical Sciences Research Council (EPSRC), UK, under the SuperGen Excitonic Solar Cell Consortium and Advantage West Midlands Science City Materials Initiative [2]
- Royal Academy of Engineering/EPSRC
- Asylum Research UK
- Engineering and Physical Sciences Research Council [EP/G031088/1] Funding Source: researchfish
- EPSRC [EP/G031088/1] Funding Source: UKRI
We report that through the incorporation of polar self-assembled monolayers (SAMs) at the indium tin oxide (ITO)/donor interface in chloroaluminium phthalocyanine (ClAlPc)/C(60) discrete heterojunction organic photovoltaic (OPV) cells, the power conversion efficiency can be dramatically increased. This enhanced performance is due to better alignment between the hole-extracting electrode Fermi level and the highest occupied molecular orbital (HOMO) of the ClAlPc donor, as well as an improved surface compatibility which provides a more optimised electrode/donor interface. Optimised cells demonstrate an increase of similar to 85% in open circuit voltage which results in a near three-fold increase in power conversion efficiency from 1.3% to 3.3% under 1 sun illumination. Comparative studies are made using cells based on two other organic donor materials, copper phthalocyanine (CuPc) and boron sub-phthalocyanine (SubPc).
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