期刊
ELECTROPHORESIS
卷 33, 期 19-20, 页码 2953-2960出版社
WILEY
DOI: 10.1002/elps.201200156
关键词
Capillary electrophoresis; Environmental waters; Field-amplified sample stacking; Inorganic selenium speciation analysis; Nanometer-sized alumina
资金
- National Nature Science Foundation of China [21175102]
- Science Fund for Creative Research Groups of NSFC [20621502, 20921062]
- MOE of China [NCET-04-0658]
In this paper, a new method of nanometer-sized alumina packed microcolumn SPE combined with field-amplified sample stacking (FASS)CE-UV detection was developed for the speciation analysis of inorganic selenium in environmental water samples. Self-synthesized nanometer-sized alumina was packed in a microcolumn as the SPE adsorbent to retain Se(IV) and Se(VI) simultaneously at pH 6 and the retained inorganic selenium was eluted by concentrated ammonia. The eluent was used for FASSCEUV analysis after NH3 evaporation. The factors affecting the preconcentration of both Se(IV) and Se(VI) by SPE and FASS were studied and the optimal CE separation conditions for Se(IV) and Se(VI) were obtained. Under the optimal conditions, the LODs of 57 ng L-1 (Se(IV)) and 71 ng L-1 (Se(VI)) were obtained, respectively. The developed method was validated by the analysis of a certified reference material of GBW(E)080395 environmental water and the determined value was in a good agreement with the certified value. It was also successfully applied to the speciation analysis of inorganic selenium in environmental water samples, including Yangtze River water, spring water, and tap water.
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