4.5 Article

Electrophoretic motion of ideally polarizable particles in a microchannel

期刊

ELECTROPHORESIS
卷 30, 期 5, 页码 773-781

出版社

WILEY
DOI: 10.1002/elps.200800381

关键词

Ideally polarizable particles; Induced-charge electrophoresis; Micro vortex; Wall effect

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The induced-charge electrophoretic (ICEP) motion of ideally polarizable particles in a microchannel is numerically studied in this paper. A complete 3-D multi-physics model is set up to simulate the transient ICEP motion of spherical ideally polarizable particles in a microchannel. The study shows that a non-uniform distribution of induced surface charge occurs when an ideally polarizable particle is immersed in an externally applied electric field, resulting in a varying slipping (EOF) velocity along the particle's surface and hence producing micro vortexes in the liquid. The numerical results verify that the steady-state ICEP velocity of an ideally polarizable particle does not differ from the electrophoretic velocity of a non-conducting particle, although the flow field near the particle does. A strong wall-repelling effect of ICEP is found when the polarizable particle is placed close to the channel wall. This is due to the lifting effect generated from the interaction between the induced micro vortexes and the channel wall and depends on the electric field and the particle size. The wall effects on ICEP motion can be used for focusing particles and for separation of particle by density.

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