期刊
JOURNAL OF PHYSICS-CONDENSED MATTER
卷 28, 期 2, 页码 -出版社
IOP PUBLISHING LTD
DOI: 10.1088/0953-8984/28/2/026005
关键词
exchange-enhanced paramagnetism; itinerate electron ferromagnetism; Stoner model; tungsten tetraboride
资金
- Chinese National Key Project for Basic Research [2014CB921002]
- National Natural Science Foundation of China [51301116, 11374225, 51502186, 11304089]
- NSF of Jiangsu [BK20130261]
- Six-Talent-Summit Project of Jiangsu [2013-XCL-038]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- USTS Cooperative Innovation Center for Functional Oxide Films and Optical Information
- 333 Project
We demonstrate that tungsten tetraboride (WB4), a heavy transition metallic compound without magnetic atoms, is an exchange-enhanced paramagnet revealed by the magnetization and specific heat measurements. WB4 has a small effective magnetic moment of 0.53 mu(B)/fu. The high magnetic susceptibility in the magnitude of 1 memu (mol.Oe)(-1) below 10 K obeys quadratic temperature dependence. The upturn behavior of C-P/T versus T-2 at low temperatures is attributed to the electron-paramagnon interactions. A high Stoner enhancement parameter, Z = 0.93, was derived to explain the enhanced paramagnetism based on the Stoner model.
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