期刊
ELECTROCHIMICA ACTA
卷 284, 期 -, 页码 202-210出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2018.07.173
关键词
Metal-organic frameworks; Ni(OH)(2) hierarchical architecture; Supercapacitor; Eco-friendly; Conformal transformation
资金
- NSFC [21371179, 21571187]
- Taishan Scholar Foundation [ts201511019]
- Fundamental Research Funds for the Central Universities [13CX05010A, 14CX02150A, 15CX02069A, 15CX06074A, 16CX02016A]
Crystallinity and surface areas play important roles on the energy storage performances of electroactive materials. Herein, a Ni-based metal-organic framework (MCF-35) is employed as the template to fabricate hierarchical Ni(OH)(2) for supercapacitor applications. By careful controlling of reaction time and pH of the reaction media, the crystallinity and surface areas of prepared Ni(OH)(2) could be tuned and an optimizing structure with balanced crystalline and surface area could be obtained. Such a structure offers high electrochemical active sites and efficient pathways for ion migration and electron transportation. Thus, a remarkable and excellent capacity of 250.6 mA h g(-1) (2255 F g(-1)) at a current density of 0.5 A g(-1) is achieved. Meanwhile, using active carbon and the optimized Ni(OH) 2 as electrodes, a hybrid supercapacitor is fabricated which exhibits an energy density of 42.54 Wh kg(-1) at the power density of 370.8W kg(-1). (C) 2018 Elsevier Ltd. All rights reserved.
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