期刊
ELECTROCHIMICA ACTA
卷 118, 期 -, 页码 92-99出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2013.11.180
关键词
Carbon past electrode; Nano-sized ion imprinted polymers; Differential pulse anodic stripping voltammetry; Lead ion
This work reports the preparation of a voltammetric sensor for selective recognition and sensitive determination of lead ions using a carbon paste electrode (CPE) impregnated with novel Pb2+-ion imprinted polymeric nanobeads (IIP) based on dithizone, as a suitable ligand for complex formation with Pb2+ ions. The differential pulse anodic stripping voltammetric technique was employed to investigate the performance of the prepared IIP-CPE for determination of hazardous lead ions. The designed modified electrode was revealed linear responses in the ranges of 3.0 x 10(-10) - 1.0 x 10(-9) mol dm(-3) and 1.0 x 10(-8) -1.0 x 10(-6) mol dm(-3) with a limit of detection (LOD) of 1.0 x 10(-10) mol dm(-3) (S/N =3). It was found that the peak currents of the modified electrode for Pb2+ ions were at maximum value in acetate buffer of pH 4.0. The optimized preconcentration potential and accumulation time were to be -1.0 V and 25 s, respectively. The applicability of the proposed sensor to lead determination in tap water and lipstick samples are reported. (C) 2013 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据