期刊
ELECTROCHIMICA ACTA
卷 125, 期 -, 页码 22-28出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2014.01.040
关键词
Li-ion capacitors; Pre-lithiation degrees; Phase transition; Mesocarbon microbeads electrode; Activated carbon electrode
资金
- National High Technology Research and Development Program of China (863) [2011AA11A232, 2013AA050905]
- National Nature Science Foundation of China [51172160, 50902102]
- Tianjin Municipal Natural Science Foundation [11JCYBJC07500]
- Tianjin High School Science & Technology Fund Planning Project [20130307]
Lithium ion capacitors are assembled with pre-lithiated mesocarbon microbeads (LMCMB) anode and activated carbon (AC) cathode. The effect of pre-lithiation degrees on the crystal structure of MCMB electrode and the electrochemical capacitance behavior of LIC are investigated by X-ray diffraction (XRD) and the charge-discharge test of three-electrode cell. The structure of graphite still maintained when the pre-lithiation capacity is less than 200 mAh g(-1), phase transition takes place with the increase of pre-lithiation capacity from 250 mAh g(-1) to 350 mAh g(-1). Pre-lithiation degrees of MCMB anode greatly affect the charge-discharge process and behavior, which impact on the electrochemical performance of LIC. The LIC with pre-lithiation capacity of 300 mAh g(-1) has the optimal electrochemical performance. The energy density of LIC300 is up to 92.3 Wh kg(-1), the power density as high as 5.5 kW kg and the capacity retention is 97.0% after 1000 cycles. The excellent electrochemical performance benefits from the appropriate pre-lithiation capacity of negative electrode. The appropriate pre-lithiation ensures the working voltage of negative electrode in low and relative stable charge-discharge platform corresponding to the mutual phase transition from the second stage graphite intercalation compound (LiC12) to the first stage graphite intercalation compound (LiCG). The stable charge-discharge platform of negative electrode is conductive to the sufficient utilization of AC positive electrode. (C) 2014 Elsevier Ltd. All rights reserved.
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