An efficient route to a hierarchical CoFe2O4@graphene hybrid films with superior cycling stability and rate capability for lithium storage

A facile, rapid, and scalable method is developed for the fabrication of hierarchical CoFe2O4@graphene (CFO@GN) hybrid films on conductive substrates as a promising binder-free lithium-ion batteries anode. The obtained films show network morphologies, and almost all of the CFO nanoparticles are also homogeneously embedded into the layered graphene network. The resulting binder-free CFO@GN electrode with 35.85 wt.% graphene exhibits excellent lithium storage performance with a high specific reversible capacity of 866.67 mAh g(-1) at a high current densities of 1000 mA g(-1), and high rate capability. In addition, the reversible capacity can retain as high as 860 mAh g(-1) and has no obvious decay after 200 cycles. This work supplies a versatile strategy for fabrication of other metal oxide@graphene hybrid films as an efficient way to improve the lithium storage performance. (C) 2014 Elsevier Ltd. All rights reserved.