期刊
ELECTROCHIMICA ACTA
卷 130, 期 -, 页码 625-633出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2014.03.070
关键词
Anion intercalation; Dual-ion cell; Graphite; Ionic liquids; Fluorosulfonyl-(trifluoromethanesulfonyl) imide
资金
- Federal Ministry of Education and Research (BMBF) within the Forderinitiative Energiespeicher [03EK3031A]
In this work, we investigate the electrochemical intercalation of the asymmetric fluorosulfonyl(trifluoromethanesulfonyl) imide (FTFSI-) anion into a graphite-based cathode for application in dual-ion cells. Since FTESI- anions are smaller than bis(trifluoromethanesulfonyl) imide (TFSI-) anions, a higher specific capacity can be expected as the decreased anion size should lead to an enhanced receptivity of the anions between the graphene sheets of graphite. The discharge capacity and the coulombic efficiency are studied at varying upper charging end potentials ranging from 4.8 V to 5.2 V vs. Li/Li+. At these varying conditions a discharge capacity of 43 mAh g(-1) to 99 mAh g(-1) is obtained, respectively. However, the increase of the upper cut-off potential leads also to a decrease of the coulombic efficiency. To gain a better insight into the influence of the anion size on the performance, FTFSI- and TESI- intercalation is discussed on a comparative basis, with respect to the potential range for anion intercalation/de-intercalation, the discharge capacity and efficiency. We observed a lower coulombic efficiency, caused by the lower electrochemical stability, as well as an enhanced discharge capacity for all investigated upper cut-off potentials for the intercalation/de-intercalation of FTESI- compared to TFSI- anion uptake/release. (C) 2014 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据