期刊
ELECTROCHIMICA ACTA
卷 133, 期 -, 页码 578-582出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2014.04.072
关键词
Lithium titanate; Mesoporous structure; Nanoparticle; Anode material; Lithium-ion battery
资金
- NSF of China [20963002, 21173088, 51003034]
- Science and Technology Planning Project of Guangdong Province [2009B010900025, 2010B080701072]
- Guangdong Natural Science Foundation [9151064201000039]
- South China Agricultural University,
- Key Laboratory of Renewable Energy and Gas Hydrate Program of the Chinese Academy of Sciences [2010002]
Mesoporous spinel lithium titanate (Li4Ti5O12) nanoparticles with the diameter of 40 +/- 5 nm and the pore-size distribution of 6 - 8 nm were prepared by a simple hydrothermal method. As an anode material for lithium-ion batteries, these spinel Li4Ti5O12 mesoporous nanoparticles exhibited desirable lithium storage properties with an initial discharge capacity of 176 mAh g(-1) at 1 C rate and a capacity of approximately 145 mAh g(-1) after 200 cycles at a high rate of 20 C. These excellent electrochemical properties at high charge/discharge rates are due to the mesoporous nano-scale structures with small size particles, uniform mesopores and larger electrode/electrolyte contact area, which shortens the diffusion path for both electrons and Li+ ions, and offers more active sites for Li+ insertion-extraction process. (C) 2014 Elsevier Ltd. All rights reserved.
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