期刊
ELECTROCHIMICA ACTA
卷 134, 期 -, 页码 182-186出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2014.04.113
关键词
Molybdenum carbide; Shape-controllable synthesis; Molybdenum oxide/p-phenylenediamine hybrid; Pyrolysis; Hydrogen evolution reaction electrocatalyst
资金
- National Natural Science Foundation of China [21175129]
- National Basic Research Program of China [2011CB935800]
- Scientific and Technological Development Plan Project of Jilin Province [20100534]
In this communication, for the first time, we demonstrate the shape-controllable synthesis of molybdenum carbide (Mo2C) nanowires (NWs) and nanosheets (NSs) via direct pyrolysis of their MoOx/p-phenylenediamine hybrid precursors under Ar. We further demonstrate the use of such carbides as a highly active hydrogen evolution reaction electrocatalyst with good durability in acidic solution. It also suggests that the Mo2C NWs exhibit superior activity and durability over the Mo2C NSs. (C) 2014 Elsevier Ltd. All rights reserved.
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