期刊
ELECTROCHIMICA ACTA
卷 129, 期 -, 页码 47-54出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2014.02.084
关键词
metal-free catalyst; nitrogen-doped carbon nanotubes; oxygen reduction reaction; catalytic effect
资金
- Malaysian Ministry of Higher Education through the Exploratory Research Grant Scheme [ERGS/1/2012/TK07/UKM/01/1]
- Universiti Kebangsaan Malaysia through the Universiti Research Grant [UKM-AP-TK-05-2009]
- Malaysian Ministry of Science, Technology and Innovation through a National Science Fellowship award
Metal-free nitrogen-doped carbon nanotube (NCNT) catalysts were synthesised via chemical vapour deposition with ethylenediamine and iron phthalocyanine. The electrochemically active NCNT was studied via thin-film rotating-ring disk voltamogram analysis to elucidate the optimum loading of catalysts for oxygen reduction reaction (ORR) in 0.1 M KOH electrolyte. In this study, the activity and stability of NCNT at elevated temperature were investigated. The current limiting plateau was achieved with loading above 500 mu g/cm(2) on glassy carbon tip with insignificant change in onset potential (c.a. +0.9 V vs RHE). The highest electron transfer number of 3.90 was obtained and it was found comparable to n = 3.95 on 130 mu g/cm(2) Pt/C catalysts. The subjection to cell's temperature from 298K to 343 K showed improved activity and was found stable above 323 K. (C) 2014 Elsevier Ltd. All rights reserved.
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