期刊
ELECTROCHIMICA ACTA
卷 147, 期 -, 页码 392-400出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2014.09.132
关键词
molybdenum disulfide; reduced graphene oxide; composite; synergetic effect; Li ion batteries
资金
- USA by Department of Defense [W911NF-12-1-0083]
- NSF-NSEC Center for Hierarchical Manufacturing Grant [CHM-CMMI-0531171]
- NSF-EPSCoR Institute for Functional Nanomaterials (IFN) [EPS-1002410, EPS-1010094]
- China by NSFC [21073096, 21421001]
- 111 Project [B12015]
- MOE Innovation Team [IRT13022]
- Office Of The Director
- EPSCoR [1010094] Funding Source: National Science Foundation
Two-dimensional MoS2 shows great potential for effective Li storage due to its good thermal and chemical stability, high theoretical capacity, and experimental accessibility. However, the poor electrical conductivity and the restacking tendency significantly restrict its applications to lithium ion batteries (LIBs). To overcome these problems, we introduced reduced graphene oxides (rGO) to the intercalation-exfoliation preparation process of few-layered MoS2 and obtained layer-by-layer MoS2/rGO hybrids. With the addition of rGO, the restacking of MoS2 layers was apparently inhibited, and MoS2 with 1 similar to 3 layers was obtained in the composite. Due to the positive role of rGO, MoS2/rGO hybrids exhibited highly enhanced cyclic stability and high-rate performances as LIB anodes in comparison with bare MoS2 layers or bulk MoS2. Moreover, the experimental results were well interpreted through density functional theory computations. (C) 2014 Elsevier Ltd. All rights reserved.
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