期刊
ELECTROCHIMICA ACTA
卷 116, 期 -, 页码 230-236出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2013.10.195
关键词
Lithium-ion batteries; Anode material; Si/Graphite@Graphene; Spray-drying
资金
- National Basic Research Program of China Major Special Plan of Science and Technology of Hunan Province, China [2011FJ1005]
Si/Graphite@Graphene composite has been prepared by an improved spray-drying method followed by heating treatment. While the thermal deposition of the precursor is determined by thermogravimetric analysis (TG-DTA), the structure of the composite is revealed by X-ray diffraction (XRD). Meanwhile, the presence of graphene is demonstrated by fourier transform infrared spectra (FI-IR) and Raman spectra studies. And scanning electron microscopy (SEM) and transmission electron microscope (TEM) images illustrate the morphology of the as-prepared material. The Si/Graphite@Graphene composite shows an enhanced electrochemical performance. At 50 mA g(-1), the Si/Graphite@Graphene sample exhibits a high initial charge capacity of 820.7 mAh g(-1), with a high initial columbic efficiency of 77.98%, the composite can still deliver high initial charge capacity of 766.2 mAh g(-1) at 500 g(-1), and shows superior cyclic and rate performance. Moreover, it has low impedance, which indicates that it could be used as a promising anode material for Li-ion batteries. (C) 2013 Elsevier Ltd. All rights reserved.
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