期刊
ELECTROCHIMICA ACTA
卷 141, 期 -, 页码 263-270出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2014.07.085
关键词
Lithium ion battery; Lithium cobalt oxide; Graphite; Vinyl ethylene carbonate; Solid electrolyte interface
资金
- National Natural Science Foundation of China [U1134002, 21273084, 21373092]
- Natural Science Foundation of Guangdong Province [U1134002, 10351063101000001]
- key project of Science and Technology in Guangdong Province [2011A010801001]
- scientific research project of Department of Education of Guangdong Province [20130CXZDA013]
We report a new finding that high voltage stability of lithium cobalt oxide (LiCoO2)/graphite battery can be improved by using vinyl ethylene carbonate (VEC) as an electrolyte additive. Charge/discharge tests demonstrate that the battery using VEC exhibits significantly improved cyclic and dimensional stability of the 053048-type LiCoO2/graphite pouch cell up to 4.5 V. The capacity retention is 87.0% and the swell value in thickness is 3.1% for the cell with 2.0 wt% VEC after 400 cycles between 3.0 V and 4.5 V, compared to the values of 38.4% and 38.6%, respectively, for the cell without additive. The characterizations from scanning electron spectroscopy and X-ray photoelectron spectroscopy demonstrate that VEC facilitates the formation of stable solid electrolyte interfaces simultaneously on anode and cathode of the LiCoO2/graphite battery, yielding effective protections for anode and cathode and preventions of the electrolyte decomposition on both electrodes. (C) 2014 Elsevier Ltd. All rights reserved.
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