期刊
ELECTROCHIMICA ACTA
卷 150, 期 -, 页码 308-313出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2014.10.149
关键词
SnO2/ZnO; electrospinning; heterogeneous nanostructure; lithium-ion batteries
资金
- National Natural Science Foundation of China [21303046]
- Research Fund for the Doctoral Program of Higher Education [20130161120014]
- China Scholarship Council [201308430178]
- Hunan University Fund for Multidisciplinary Developing [531107040762]
- Hunan Provincial Innovation Foundation for Postgraduate [521293041]
The ZnO/SnO2 heterogeneous nanofibers (HNFs) have been prepared via an electrospinning method followed by calcination at 500 degrees C in air. XRD, BET, SEM, TEM and electrochemical measurements were performed to characterize the new material, including structure, morphology and electrochemical properties. The spacing between adjacent SnO2 nanorods on mesoporous ZnO nanofibers is about twice the diameter of each SnO2 nanorod. The SnO2/ZnO11 (molar ratio of Sn: Zn = 1: 1) HNFs based electrodes exhibit excellent cycle performance and rate performance, which is attributed to the heterogeneous and mesoporous structure as well as the ultrafine ZnO NPs embedded in the HNFs matrix. Outstanding electrochemical performance as anode material for LIBs together with low cost, facile procedures and high reproducibility make the SnO2/ZnO HNFs have a prospect in the field of energy storage. Crown Copyright (C) 2014 Published by Elsevier Ltd. All rights reserved.
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