期刊
ELECTROCHIMICA ACTA
卷 109, 期 -, 页码 46-51出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2013.07.060
关键词
Electrochemistry; Li-ion battery; Sn anode; Cu6Sn5; SnO
资金
- National Natural Science Foundation of China [51274058]
To compare cyclic performances of different Sn based materials as anodes for Li ion battery and minimize the influence from processing conditions, the SnO/Sn/Cu6Sn5 three-layer film was prepared by a facile method of annealing the electrodeposited thick Sn film on Cu substrate at 200 degrees C in atmosphere for 48 h. Microstructure and morphology of the three-layer film were characterized by X-ray diffraction and SEM. Both the Sn film and three-layer film were assembled as anodes in Li-ion battery. Their electrochemical properties were studied by charge/discharge, cyclic voltammetry and ac impedance spectra. Compared with Sn anode, SnO/Sn/Cu6Sn5 three-layer anode shows much smaller SEI film, charge transfer and diffusion resistance. Capacities of SnO, Sn and Cu6Sn5 phases were obtained from analysis of charge/discharge curves. Among all three phases, Cu6Sn5 shows both the highest capacity and capacity retention. (C) 2013 Elsevier Ltd. All rights reserved.
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