期刊
ELECTROCHIMICA ACTA
卷 100, 期 -, 页码 275-280出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2012.05.073
关键词
Ionic liquid; Chitosan; Gel electrolyte; Electric double-layer capacitor
资金
- Grants-in-Aid for Scientific Research [23655182] Funding Source: KAKEN
Nonaqueous gel electrolytes based on chitosan and 1-ethyl-3-methylimidazolim tetrafluoroborate (Chi/EMImBF(4)) are prepared for electric double-layer capacitors (EDLCs). The transparent colorless gel sheet has the high levels of mechanical strength and ionic liquid retention required in EDLC cells. Charge discharge measurements revealed that a model EDLC cell with a chitosan gel exhibits high discharge capacitance although a gel-state electrolyte was used, indicating that the high affinity of chitosan for the activated carbon electrode decreases the electrode electrolyte interfacial resistance. A test cell with Chi/EMImBF(4) maintained a Coulombic efficiency of more than 99.9% during 5000 cycles. (C) 2012 Elsevier Ltd. All rights reserved.
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