期刊
ELECTROCHIMICA ACTA
卷 93, 期 -, 页码 230-235出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2013.01.100
关键词
Polymer electrolyte; Ionic conductivity; Lithium salts; X-ray diffraction analysis; AC impedance
Plasticised polymer blend electrolytes based on poly(vinylidenefluoride-co-hexafluoropropylene) (PVdF-co-HFP) and poly(ethyl methacrylate) (PEMA) were prepared for different lithium salts LiX (X=ClO4, CF3SO3, BE4 and N[CF3SO2](2)) using facile solution casting. To confirm the structures and complexations of the electrolyte films, the prepared electrolytes were subjected to XRD and FTIR analysis. TG-DTA was used to ascertain the thermal stability of the electrolytes, and the porous nature of the electrolytes was identified using scanning electron microscopy via ion-hopping conduction. AC impedance analysis was performed for all the electrolyte samples at various temperatures from 303 to 363 K. The results suggest that among the various lithium salts, LiN[CF3SO2](2)-based electrolytes exhibited the highest ionic conductivity (0.918 x 10(-3) S cm(-1)). The temperature dependence of the ionic conductivity also complies with the VTF relation. (C) 2013 Elsevier Ltd. All rights reserved.
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