期刊
ELECTROCHIMICA ACTA
卷 111, 期 -, 页码 656-662出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2013.08.019
关键词
Stellite 6 alloy; Corrosion behaviour; Sodium chloride solution; Electrochemical impedance spectroscopy (EIS); Passive film
Cobalt-base (Stelae) alloys have seen extensive use in wear environments mainly due to their high strength, corrosion resistance and hardness. Co-base superalloys rely primarily on carbides formed in the Co matrix and at grain boundaries, for their strength and wear resistance. The distribution, size and shape of carbides depend on processing conditions. Currently, the use of Stellite alloys has extended into various industrial sectors (e.g. pulp and paper processing, oil and gas processing, pharmaceuticals, chemical processing) and the need for improved information regarding corrosion of Stellite alloys has increased. It has been recognized that processing changes, which affect the microstructure of Stellite alloys, most affect corrosion resistance. In this work the corrosion behaviour of Stellite 6 alloy in the as-cast and the HIPed consolidated forms is compared and contrasted using DC and AC electrochemical techniques in static saline conditions. The results show that there is a significant difference in the corrosion performance of HIP consolidated Stellite 6 and it is possible to link the corrosion behaviour to the microstructure. The benefits of using HIPing as a manufacturing process for the corrosion performance of Stellite 6 are discussed. (C) 2013 Elsevier Ltd. All rights reserved.
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