期刊
ELECTROCHIMICA ACTA
卷 99, 期 -, 页码 161-165出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2013.03.088
关键词
Oxygen reduction; Manganese dioxide; Chemical synthesis; Catalyst; Zinc-air battery
资金
- National Natural Science Foundation of China [21273084]
- Natural Science Foundation of Guangdong Province [10351063101000001]
- Cooperation Project of Industries, Universities and Research Institutes in Guangdong Province [2011B090400317]
Four MnO2 samples were synthesized through a simple reaction of KMnO4 with high-purity graphite in different concentrations of sulfuric acid at low temperature. Their morphology, crystal structure and performance as cathode catalysts of zinc-air battery were investigated with X-ray diffraction (XRD), Fourier transformation infrared spectrometer (FTIR), scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET) and electrochemical tests. It is found that the crystal structure and the morphology of the synthesized samples depend on the sulfuric acid concentration. The synthesized samples have large specific surface area and exhibit excellent performance compared to the commercial electrolytic manganese dioxide (gamma-MnO2). Two varieties of manganese dioxides, delta-MnO2 (the as-prepared samples a and b) and alpha-MnO2 (the as-prepared sample c and d), were obtained when using low and high sulfuric acid concentration, respectively. Higher sulfuric acid concentration favors the agglomeration of the particles. The specific surface area of samples a, b, c, d, and gamma-MnO2 is 83.2, 81.1, 88.5, 86.8, and 43.5 m(2) g(-1), corresponding to discharge capacity of zinc-air batteries is 169.5, 160.3, 175.2, 171.5, and 112.2 mAh, respectively. (C) 2013 Elsevier Ltd. All rights reserved.
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