A nanoparticle Mg-doped Li4Ti5O12 for high rate lithium-ion batteries

A nanoparticle Mg-doped Li4Ti5O12 with a grain size of 20-30 nm has been successfully synthesized through a simple hydrothermal method. The first-principle simulations are employed to theoretically study the crystal structure, unit cell volume, lattice parameters, and band gaps. Galvanostatic charge-discharge tests have been carried out, using the as-prepared Li4Ti5O12 and Mg-doped Li4Ti5O12 as the working electrodes with a voltage range of 0.5-2.5 V vs. Li+/Li. The tests show promising results with high capacity and long term stability. When discharging at 350 mAg(-1) (corresponding to a 2 C rate), the discharge capacity remains at 170 mAhg(-1) over 100 cycles. As the C-rate rises to an ultrafast charge-discharge rate of 50 C, the discharge capacity can still retain at 115 mAhg(-1). The excellent electrochemical performance is due to both the nanomorphology and better conductivity after Mg doping. The results show that the Mg-doped Li4Ti5O12 can act as a fast charge-discharge anode material for high rate lithium-ion batteries (LIBs). (C) 2013 Elsevier Ltd. All rights reserved.