期刊
ELECTROCHIMICA ACTA
卷 59, 期 -, 页码 160-167出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2011.10.055
关键词
Carbon nanotubes; Tin oxide; Core-shell composites; Anode; Lithium-ion batteries
资金
- National Natural Science Foundation of China [50572003, 50972004]
- Xinjiang Key Laboratory of Electronic Information Materials and Devices [XJYS0901-2010-03]
- Foundation of Excellent Doctoral Dissertation of Beijing City [YB20081001001]
Carbon nanotube-encapsulated SnO2 (SnO2@CNT) core-shell composite anode materials are prepared by chemical activation of carbon nanotubes (CNTs) and wet chemical filling. The results of X-ray diffraction and transmission electron microscopy measurements indicate that SnO2 is filled into the interior hollow core of CNTs and exists as small nanoparticles with diameter of about 6 nm. The SnO2@CNT composites exhibit enhanced electrochemical performance at various current densities when used as the anode material for lithium-ion batteries. At 0.2 mA cm(-2) (0.1C), the sample containing wt. 65% of SnO2 displays a reversible specific capacity of 829.5 mAh g(-1) and maintains 627.8 mAh g(-1) after 50 cycles. When the current density is 1.0, 2.0, and 4.0 mA cm(-2) (about 0.5, 1.0, and 2.0C), the composite electrode still exhibits capacity retention of 563, 507 and 380 mAh g(-1), respectively. The capacity retention of our SnO2@CNT composites is much higher than previously reported values for a SnO2/CNT composite with the same filling yield. The excellent lithium storage and rate capacity performance of SnO2@CNT core-shell composites make it a promising anode material for lithium-ion batteries. (C) 2011 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据