Synthesis of mesoporous NiO nanospheres as anode materials for lithium ion batteries

In this work, three-dimensional mesoporous NiO nanostructures have been synthesized by a simple ethylene glycol (EG)-mediated self-assembly route and subsequent calcination process. The synthesized nickel alkoxide precursors annealed at 300 and 500 degrees C exhibit different surface area, crystallinity and pore distribution, which have been characterized by scanning electron microscopy, transmission electron microscopy, selected area electron diffraction, X-ray diffraction, Fourier transform infrared spectroscopy and Nitrogen adsorption/desorption isotherms. The electrochemical properties of these NiO mesoporous nanostructures are investigated including the cycling and rate performance as anode materials for lithium-ion batteries. It is indicated that mesoporous NiO nanospheres synthesized at 500 degrees C exhibit better electrochemical performance than that obtained at 300 degrees C. The NiO nanospheres annealed at 500 degrees C present a reversible specific capacity of 518 mAh g(-1) at a current density of 0.1 A g(-1) after 60 cycles. With varying the rate from 0.1 to 8.0 A g(-1), the capacity remains at 535 mAh g(-1) at 2 A g(-1) after 30 cycles and resumes to 582 mAh g(-1) at 0.1 A g(-1) after 60 cycles. The results indicate that our mesoporous NiO nanospheres are promising anode materials for lithium ion batteries. (C) 2012 Elsevier Ltd. All rights reserved.