期刊
ELECTROCHIMICA ACTA
卷 63, 期 -, 页码 302-311出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2011.12.103
关键词
Nanoporous silver; Dealloying; Zn-Ag alloys; Potentiodynamic polarization; Potentiostatic polarization
资金
- National Natural Science Foundation of China [50971079]
- Program for New Century Excellent Talents in University
- Independent Innovation Foundation of Shandong University [2010JQ015]
The electrochemical dealloying of rapidly solidified (RS) Zn-Ag alloys in a 5 wt.% HCl solution and 1 M NaCl solution has been investigated using electrochemical measurements and microstructural analysis. The results show that the electrochemical properties of the RS Zn-Ag alloys are associated not only with the alloy composition, but with the phase constitution of the alloys. Nanoporous silver (NPS) ribbons can be fabricated through potentiostatically dealloying the RS Zn-Ag alloys in both solutions. Moreover, a minor difference in the applied potential has a significant influence on the dealloying process and formation of NPS. The critical potential and polarization behavior of the Zn-Ag alloys have also been discussed, as well as surface diffusion of Ag adatoms. (C) 2011 Elsevier Ltd. All rights reserved.
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