4.6 Article

Sulfur-carbon composite electrode for all-solid-state Li/S battery with Li2S-P2S5 solid electrolyte

期刊

ELECTROCHIMICA ACTA
卷 56, 期 17, 页码 6055-6059

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2011.04.084

关键词

Lithium battery; All-solid-state battery; Li/S cell; Mechanical milling; Sulfide solid electrolyte

资金

  1. Japan Science and Technology Agency (JST), Core Research for Evolutional Science and Technology (CREST)
  2. Grants-in-Aid for Scientific Research [21246098, 10J08610] Funding Source: KAKEN

向作者/读者索取更多资源

All-solid-state Li/S batteries with Li2S-P2S5 glass-ceramic electrolytes were fabricated and their electro-chemical performance was examined. Sulfur-carbon composite electrodes were prepared by grinding with a mortar and milling with a planetary ball-mill apparatus. Milling of a mixture of sulfur, acetylene black and the Li2S-P2S5 glass-ceramic electrolyte resulted in the amorphization of sulfur and a reduction in the particle size of the mixture. The charge-discharge properties of all-solid-state cells with the composite electrode were investigated at temperatures from -20 degrees C to 80 degrees C. The cells retained a reversible capacity higher than 850 mAhg(-1) for 200 cycles under 1.3 mA cm(-2) (333 mA g(-1)) at 25 degrees C. The cell performance was influenced by the crystallinity of sulfur and the particle size of the electrode material, whereby improved contact among the electrode components achieved by milling contributed to enhancement of the capacity of an all-solid-state Li/S cell. (C) 2011 Elsevier Ltd. All rights reserved.

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