A low-potential, H2O2-assisted electrodeposition of cobalt oxide/hydroxide nanostructures onto vertically-aligned multi-walled carbon nanotube arrays for glucose sensing

A novel nanocomposite was synthesized using a cathodic, low-potential, electrochemical reduction of H2O2 to homogeneously deposit cobalt oxide/hydroxide (denoted as CoOx center dot nH(2)O) nanostructures onto vertically well-aligned multi-walled carbon nanotube arrays (MWCNTs), while the MWCNTs were prepared by catalytic chemical vapor deposition (CVD) on a tantalum (Ta) substrate. The CoOx center dot nH(2)O-MWCNTs nanocomposite exhibits much higher electrocatalytic activity towards glucose (Glc) after modification with CoOx center dot nH(2)O than before. This non-enzymatic Glc sensor has a high sensitivity (162.8 mu A mM(-1) cm(-2)), fast response time (<4 s) and low detection limit (2.0 mu M at signal/noise ratio = 3), and a linear dynamic range up to 4.5 mM. The sensor output is stable over 30 days and unaffected by common interferents that co-exist with Glc in analytical samples; it is also resistant to chloride poisoning. These features make the CoOx center dot nH(2)O-MWCNTs nanocomposite a promising electrode material for non-enzymatic Glc sensing in routine analysis. (C) 2011 Elsevier Ltd. All rights reserved.